Dinuclear Molybdenum(II) Complexes with Thioether Functionalized Silylamide Ligands
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چکیده
منابع مشابه
Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties
Four dimeric nickel(II) complexes [Ni2Cl2(BnC2S)2] [1], [Ni2Cl2(BnC3S)2] [2], [Ni2(PyC2S)2]Br2 [3]Br2, and [Ni2(PyC3S)2]Br2 [4]Br2 of four different thiolate-functionalized N-heterocyclic carbene (NHC) ligands were synthesized, and their structures have been determined by single-crystal X-ray crystallography. The four ligands differ by the alkyl chain length between the thiolate group and the b...
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The reactions of 2-(mercaptoethyl)benzimidazole with 2-vinylpyridine and 2-picolyl chloride (in basic medium) yield the new unsymmetrical ligands 1-(2-benzimidazolyl)-5-(2 -pyridyl)-3-thiapentane (Biptp) and 1-(2-benzimidazolyl)-4-(2 -pyridyl)-3-thiabutane (Biptb), respectively. Copper(II) complexes of these ligands with differing anions were prepared. Crystal structures are reported for [Cu(Bi...
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Reaction of Dy(hfac)(3)·2H(2)O (hfac = hexafluoroacetyl acetonate) with 2-(2-hydroxyphenyl)nitronyl nitroxide (NITPhOH) and 2-(5-bromo-2-hydroxyphenyl)nitronyl nitroxide (NIT5BrPhOH) yielded [Dy(2)(hfac)(4)(NITPhO)(2)] 1 and [Dy(2)(hfac)(4)(NIT5BrPhO)(2)] 2, respectively. These compounds are phenoxo-O bridged binuclear complexes with the radical unit of a ligand coordinated to a single Dy. The ...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2019
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.201900235